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Wikipedia
The second law of thermodynamics states that the total entropy of an
isolated system can only increase over time. It can remain constant in
ideal cases where the system is in a steady state (equilibrium) or
undergoing a reversible process. The increase
in entropy accounts for the irreversibility of natural processes, and the
asymmetry between future and past. Historically, the second law was
an empirical finding that was accepted as an axiom of thermodynamic
theory. Statistical thermodynamics, classical or quantum, explains the
microscopic origin of the law. The second law has been expressed in many
ways. Its first formulation is credited to the French scientist Sadi
Carnot in 1824, who showed that there is an upper limit to the efficiency
of conversion of heat to work in a heat engine.
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